Electrochemical studies of glutathione monolayer assembled on a polycrystalline gold electrode

The glutathione (GSH) monolayer and complex monolayer of GSH-metallic ion on polycrystalline gold electrode were studied by using K₃Fe(CN)₆ as the redox probe. As for the GSH monolayer, it was found that the metallic ions could open the ion-gate in the monolayer dramatically in the order La³⁺> Pb²⁺>>Ba²⁺>Ca²⁺ whereas Zn²⁺ ion closed the ion-gate. The complexes of GSH-metallic ions were capable of self-assembling the different kind of monolayer. All the differences were related to the structural configuration of the anchored GSH molecule, which changed with different metallic ions or pH. Biography:Fang Cheng (1971-) male, Ph. D, research direction: electroanlysis.     

基于线性元的电阻抗成像的数学模型和算法

本文讨论了电阻抗成像的数学模型，先利用有限元方法将其离散化，再把它转化为非线性优化问题，并给出了利用牛顿法求解这一问题的具体算法．最后进行了一系列数值仿真对比实验，证实了这一算法的有效性，指出了其中存在的问题．     

单涂层吸波材料的优化设计及偏差研究

本文通过对单涂层吸波材料内电磁波传输损耗机理的细致研究，提出了单涂层吸波材料优化设计的两项原则。结合具体实例详细说明这两项原则的具体应用，最后讨论涂层电磁参量在偏离匹配条件的情况下，对涂层吸波性能影响的具体结果分析。图３．表１，参３。     

高功率型镍氢电池的循环性能

由于没有镉污染,对环境友好,用于高功率设备的镍氢电池的需求量增长很快,目前每年的需求量约为5亿只.但是镍氢电池的一些性能还不能完全满足电动工具的使用要求,突出表现在电池大电流充放循环寿命较差.因此,研制高性能的高倍率镍氢电池不仅具有重要的研究意义,也有很大的应用价值.本文研究影响SC型动力电池循环寿命衰减的主要因素,测量了在大电流循环过程中镍氢电池的内阻、温度及重量变化,并运用SEM、XRD对电池内阻升高的原因进行了分析.我们认为电池内阻升高是镍氢电池大电流循环寿命差的主要原因,分析发现在镍氢电池进行大电流充放电循环时,电池正极膨胀,负极微粉化,电池内部孔隙率增加,致使电解液干涸,电池内阻升高.通过增加负极容量,抑制正极膨胀,可以有效改进镍氢电池大电流充放时的循环性能.     

反馈网络中电位器对调节器性能的影响

通过对各种类型的调节器中含有电位器时传递函数的求解分析,得出接入电位器后对调节器的比例放大系数、微分时间常数及积分时间常数的影响结果,并使多种调节器在形式上得到了统一,根据需要可方便地调节电位器使其性能达到设计的需要.     

特定最大功率传输问题探讨

本文通过理论计算给出几种特定情况下的功率传输问题。     

APPLICATION OF MECHANICAL IMPEDANCE IN VIBRATION ANALYSIS

In the network of a mechanical system,force F and velocity V are related by mechanicalimpedance Z as:Z=F/V.In this paper,we are going to discuss two cases:①Z=0,which gives the frequency equation of the system.We shall use this equation tosolve some practical examples;②Z=∞,which can serve as the design criterion of dynamic dampers.     

覆冰地区分裂与扩径导线表面电场特性

输电线路覆冰对电力系统安全运行具有严重威胁,目前已经发展了多种防冰除冰方法,但每种方法都有其局限性,对于一些具有微气象、微地形特征的重覆冰地区尚未有较好的解决方法。文中考虑到扩径导线的特点和分裂导线输电线路的局限性,根据波阻抗和自然功率将分裂导线等效为单导线,并考虑电流的集肤效应,得到了等效的单根扩径导线,进而分析比较覆冰地区的分裂导线及其等效的单根扩径导线的表面电场特性。研究表明：等效前后导线截面面积相同且波阻抗一致时,扩径导线与分裂导线相比,不仅显著降低了子导线根数和输电线路的覆冰荷载,而且在扩径导线的半径等于分裂导线的等效单导线半径时,扩径导线的表面最大电场强度小于分裂导线。因此,在严重覆冰地区,采用分裂导线等效半径的扩径导线具有非常好的表面电场特性,且可显著降低冰风荷载,提高抗冰强度。     

New evidence for the Qinghai-Xizang (Tibet) Plateau as a pilot region of climatic fluctuation in China

Over 40 a observed temperature data in 172 stations in China and historical proxy data were analyzed. Evidence suggested that during 1980–1994, the warmest year appeared first in southeastern part of the Qinghai-Xizang (Tibet) Plateau (henceforth SETP) and then gradually spread northwards and eastwards to eastern China. The climatic change on century time scale in recent 600 a shows 3 relatively warm and clod stages in China. Each warm and cold stage appeared first in Tibet Plateau (henceforth TP) and then in the Qilian Mountains, then in the eastern parts of China. The warm and cold stages in TP were 10–60 a earlier than in the eastern China. The facts show that TP is a pilot region of climatic fluctuation in China on the time scale shorter than 10³a.     

利用阻抗谱测定氧化锆试样的电导率

利用阻抗谱测定了2.18%MgO稳定的ZrO2试样在空气中的电导率随温度的变化曲线。结果表明,在1165~1 730 K温度变化范围内,电导率在6.0×10-4~3.3×10-2S.cm-1范围内变化;电导率随温度变化曲线可分为4段,其中,在1 423~1 523 K范围内发生单斜相向四方相的转变,1 673 K以上存在四方相向立方相的转变,导致电导率的跳跃升高。